Đáp án C

$NaOH + HCl \to NaCl + H_2O$
$n_{HCl\ dư} = n_{NaOH} = 0,05.2 = 0,1(mol)$

Gọi $n_{Fe} = a ; n_{Zn} = b \Rightarrow 56a + 65b = 12,1(1)$

$Fe + 2HCl  \to FeCl_2 + H_2$
$Zn + 2HCl \to ZnCl_2 + H_2$
$n_{HCl} = 2a + 2b = 0,5  -0,1 = 0,4(2)$

Từ (1)(2) suy ra  a = b = 0,1

$\%m_{Fe} = \dfrac{0,1.56}{12,1}.100\% = 46,28\%$

$\%m_{Zn} = 100\% -46,28\% = 53,72\%$

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(HCl_{dư}+NaOH\rightarrow NaCl+H_2O\)

Gọi x, y lần lượt là số mol Fe, Zn, theo đề ta có:

\(\left\{{}\begin{matrix}56x+65y=12,1\\2x+2y=0,5.1-0,05.2\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

=> \(\%m_{Fe}=\dfrac{0,1.56}{12,1}=46,28\%\)

=> \(\%m_{Zn}=100-46,28=53,72\%\)

a, Ta có: 27n_Al + 56n_Fe = 22 (1)

PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{19,832}{24,79}=0,8\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4\left(mol\right)\\n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)

b, \(n_{HCl}=2n_{H_2}=1,6\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,5}=3,2\left(M\right)\)

a) Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow24a+27b=5,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Bảo toàn electron: \(2a+3b=0,5\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%\approx47,06\%\\\%m_{Al}=52,94\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\)

\(\Rightarrow V_{HCl}=\dfrac{250}{1,2}\approx208,33\left(ml\right)\)